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Chemistry

A-Level Chemistry is the study of matter, its structure, its transformations and the energy that accompanies them, set against the Department for Education GCE AS and A level subject content and delivered here through the AQA 7405 specification. It runs from atomic structure, amount of substance, bonding and energetics through kinetics, equilibria and redox, up to thermodynamics, electrode potentials, acid-base equilibria, the periodic table and the transition metals, and the whole sweep of organic chemistry from alkanes to aromatics, polymers, amino acids and the spectroscopic methods used to determine structure. It is assessed as much on the application of chemical ideas to unfamiliar contexts and the analysis of experimental and spectroscopic data as on recall.

0/81 Texts·18 Chapters·~244 min total

Continue reading — Chapter ITable of contents
LPAQA 7405 3.1.1.1LPDfE GCE Chemistry - atomic structureLPAQA 7405 3.1.1.2LPDfE GCE Chemistry - mass spectrometryLPDfE GCE Chemistry - relative atomic massLPAQA 7405 3.1.1.3+142 more●○○Foundation●●○Standard●●●Advanced
Table of contents · 18 ChaptersT·18
Ch. IAtomic structure5 texts · 0 read
  • Fundamental particles, mass number and isotopesText L·01 · Recommended start3 min
  • Time-of-flight mass spectrometryText L·024 min
  • Relative atomic mass from mass spectraText L·033 min
  • Electron configuration: shells, sub-shells and orbitalsText L·043 min
  • Ionisation energies as evidence for structureText L·054 min
Ch. IIAmount of substance5 texts · 0 read
  • Relative masses and the moleText L·063 min
  • The ideal gas equation and molar volumeText L·073 min
  • Empirical and molecular formulaeText L·083 min
  • Equations, reacting masses, atom economy and yieldText L·093 min
  • Solutions, concentration and titrationsText L·103 min
Ch. IIIBonding5 texts · 0 read
  • Ionic bonding and giant ionic latticesText L·113 min
  • Covalent and dative covalent bondingText L·123 min
  • Metallic bonding and the four structuresText L·133 min
  • Shapes of molecules and ions (electron-pair repulsion)Text L·143 min
  • Electronegativity, polarity and intermolecular forcesText L·154 min
Ch. IVEnergetics4 texts · 0 read
  • Enthalpy change and reaction profilesText L·163 min
  • Standard enthalpy changes and calorimetryText L·173 min
  • Hess's law and enthalpy cyclesText L·183 min
  • Mean bond enthalpies and their limitationsText L·193 min
Ch. VKinetics4 texts · 0 read
  • Collision theory and activation energyText L·203 min
  • The Maxwell-Boltzmann distributionText L·213 min
  • Temperature, concentration and rateText L·223 min
  • Catalysts and the distributionText L·233 min
Ch. VIChemical equilibria, Le Chatelier's principle and Kc4 texts · 0 read
  • Dynamic equilibrium in a closed systemText L·243 min
  • Le Chatelier's principleText L·253 min
  • The equilibrium constant KcText L·263 min
  • Industrial processes and compromise conditionsText L·273 min
Ch. VIIOxidation, reduction and redox equations4 texts · 0 read
  • Oxidation and reduction as electron transferText L·282 min
  • Oxidation states and the assignment rulesText L·293 min
  • Oxidising and reducing agentsText L·303 min
  • Half-equations and balanced redox equationsText L·313 min
Ch. VIIIPeriodicity3 texts · 0 read
  • The Periodic Table and the s, p and d blocksText L·322 min
  • Trends in atomic radius and ionisation energy across Period 3Text L·333 min
  • Trends in melting point across Period 3Text L·343 min
Ch. IXGroup 2, the alkaline earth metals4 texts · 0 read
  • Trends in physical properties down Group 2Text L·353 min
  • Reactions with water and reactivityText L·363 min
  • Solubility trends of hydroxides and sulfatesText L·373 min
  • Uses of Group 2 compoundsText L·383 min
Ch. XGroup 7(17), the halogens4 texts · 0 read
  • Trends in electronegativity and boiling pointText L·393 min
  • Halogens as oxidising agents and displacement reactionsText L·403 min
  • Halides as reducing agents with concentrated sulfuric acidText L·413 min
  • Testing for halide ions and disproportionation of chlorineText L·423 min
Ch. XIIntroduction to organic chemistry5 texts · 0 read
  • Functional groups, homologous series and general formulaeText L·433 min
  • Nomenclature and formulae of organic compoundsText L·443 min
  • Structural isomerismText L·452 min
  • E-Z stereoisomerismText L·463 min
  • Reaction mechanisms and reagent typesText L·473 min
Ch. XIIAlkanes, halogenoalkanes, alkenes and alcohols5 texts · 0 read
  • Alkanes: distillation, cracking, combustion and free-radical substitutionText L·483 min
  • Halogenoalkanes: nucleophilic substitution and eliminationText L·493 min
  • Alkenes: electrophilic addition and Markownikoff's ruleText L·503 min
  • Addition polymersText L·513 min
  • Alcohols: production, oxidation and dehydrationText L·523 min
Ch. XIIIOrganic analysis4 texts · 0 read
  • Test-tube reactions for functional groupsText L·533 min
  • Mass spectrometry of organic moleculesText L·543 min
  • Infrared spectroscopy and the greenhouse effectText L·553 min
  • Combining evidence to determine a structureText L·563 min
Ch. XIVThermodynamics, rate equations and further equilibria (A-level)7 texts · 0 read
  • Born-Haber cycles and enthalpies of solution and hydrationText L·573 min
  • Entropy and Gibbs free energyText L·584 min
  • Rate equations, orders and the Arrhenius equationText L·594 min
  • Kp for homogeneous gaseous equilibriaText L·603 min
  • Electrode potentials and electrochemical cellsText L·613 min
  • pH, Ka and the ionic product of waterText L·623 min
  • Buffers, titration curves and indicatorsText L·633 min
Ch. XVPeriod 3 elements, transition metals and reactions of ions in solution (A-level)5 texts · 0 read
  • Period 3 elements and their oxidesText L·643 min
  • The transition metals: definition and propertiesText L·652 min
  • Complex ions, shape and isomerismText L·663 min
  • Colour, variable oxidation states and catalysisText L·673 min
  • Reactions of metal-aqua ions in aqueous solutionText L·683 min
Ch. XVIOptical isomerism, carbonyls, carboxylic acids and aromatic chemistry (A-level)5 texts · 0 read
  • Optical isomerism and chiralityText L·693 min
  • Aldehydes and ketones: nucleophilic addition and testsText L·703 min
  • Carboxylic acids and their derivativesText L·713 min
  • Aromatic chemistry: benzene and electrophilic substitutionText L·723 min
  • Amines: base strength and reactionsText L·733 min
Ch. XVIIPolymers, amino acids, proteins and DNA, and organic synthesis (A-level)4 texts · 0 read
  • Addition and condensation polymersText L·743 min
  • Amino acids, proteins and enzymesText L·753 min
  • DNA and the action of cisplatinText L·763 min
  • Organic synthesis and functional-group interconversionText L·773 min
Ch. XVIIINMR spectroscopy and chromatography (A-level)4 texts · 0 read
  • The principle of NMR and the chemical shiftText L·783 min
  • Carbon-13 NMR and carbon environmentsText L·793 min
  • Proton NMR: integration and spin-spin splittingText L·803 min
  • Chromatography: TLC, column and gas chromatographyText L·813 min
Reading progress · subject
—Read
0/81
Texts
~244
min total
Recommended start
Atomic structure · Ch. I
Fundamental particles, mass number and isotopes
Text L·01 · 3 min
Read now
Instrument · 01Recommended study order
  1. 1Atomic structure
  2. 2Amount of substance
  3. 3Bonding
  4. 4Energetics
  5. 5Kinetics
  6. 6Chemical equilibria, Le Chatelier's principle and Kc
  7. 7Oxidation, reduction and redox equations
  8. 8Periodicity
  9. 9Group 2, the alkaline earth metals
  10. 10Group 7(17), the halogens
  11. 11Introduction to organic chemistry
  12. 12Alkanes, halogenoalkanes, alkenes and alcohols
  13. 13Organic analysis
  14. 14Thermodynamics, rate equations and further equilibria (A-level)
  15. 15Period 3 elements, transition metals and reactions of ions in solution (A-level)
  16. 16Optical isomerism, carbonyls, carboxylic acids and aromatic chemistry (A-level)
  17. 17Polymers, amino acids, proteins and DNA, and organic synthesis (A-level)
  18. 18NMR spectroscopy and chromatography (A-level)
Instrument · 02Exam structure
Paper 1 - Inorganic and physical chemistry (AQA 7405/1)
2 hours, 105 marks, 35% of the A-Level. Assesses the physical chemistry of atomic structure, amount of substance, bonding, energetics, equilibria and Kc, redox, thermodynamics, rate equations, Kp, electrode potentials and acid-base equilibria (specification 3.1.1-3.1.4, 3.1.6-3.1.8 and 3.1.10-3.1.12) together with the whole of inorganic chemistry (periodicity, Groups 2 and 7, Period 3 and the transition metals, 3.2). Structure: 105 marks of short and long answer questions. A scientific calculator is allowed on every paper and a Periodic Table is provided.
Paper 2 - Organic and physical chemistry (AQA 7405/2)
2 hours, 105 marks, 35% of the A-Level. Assesses the physical chemistry of amount of substance, bonding, energetics, kinetics and equilibria (3.1.2-3.1.6) and rate equations (3.1.9), together with the whole of organic chemistry from nomenclature and the core homologous series to aromatics, amines, polymers, amino acids and the analytical and spectroscopic methods (3.3). Structure: 105 marks of short and long answer questions.
Paper 3 - Synoptic and practical (AQA 7405/3)
2 hours, 90 marks, 30% of the A-Level. Draws on any content from across the whole course: 40 marks of questions on practical techniques and data analysis, 20 marks of questions testing synoptic understanding across the specification, and 30 marks of multiple-choice questions. This is the paper where the twelve required practicals and the handling of real data are most heavily rewarded.
Assessment objectives, practical endorsement and grading
Across the three papers the assessment objectives are weighted towards application and analysis rather than recall: AO1 (knowledge and understanding) is roughly a third of the marks, AO2 (application) the largest single share, and AO3 (analyse, interpret and evaluate) the remainder. At least 20% of the marks assess level-2 mathematical skills - the highest mathematical demand of the three sciences - and at least 15% assess practical knowledge and skills. The separately reported Practical Endorsement (pass / not classified) is based on twelve required practical activities judged against the Common Practical Assessment Criteria (CPAC). The full A-Level is linear, sat at the end of the course, and graded A*-E (U below E).
Instrument · 03Official sources
  • GCE AS and A level subject content for biology, chemistry, physics and psychologyDepartment for Education
  • AQA AS and A-level Chemistry (7404 / 7405) specificationAQA

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